Hollywood siren Angelina Jolie has been named the Most Beautiful Woman in the World, beating supermodel Gisele Bundchen to the top spot in a new Vanity Fair poll.

The Wanted star was by far the most popular celebrity, garnering 58 per cent of the vote compared to newlywed Bundchen's nine per cent and third-placed Halle Berry with four per cent.

Brazilian stunner Bundchen, who recently married American footballer Tom Brady, wasn't the only one of actor Leonardo DiCaprio's lovers to make the list - current girlfriend Bar Refaeli tied for fourth place with Penelope Cruz, Scarlett Johansson and Jennifer Connelly with three per cent each.

Other celebrities to make the countdown include Beyonce Knowles, Slumdog Millionaire actress Freida Pinto, Kerry Washington and Gwyneth Paltrow.

Angelina Jolie Photos

(This news article provided by World Entertainment News Network)