In the final and fifth season of La Femme Nikita, beautiful and deadly Nikita - wrongly accused of murder and sentenced to life in prison only to be enlisted as a top secret agent by a clandestine government organization known as Section One - uncovers the mole inside Section One and also discovers why she was enlisted as an assassin. Also on DVD: Big Love season 1, CSI: NY season 2, Starsky & Hutch and "Murder She Wrote" season 5, and Charmed season 6.