Ariana Grande went all "Fifty Shades Of Grey" on the red carpet prior to the 2014 MTV Video Music Awards, wearing a strapless black leather mini-dress and black leather thigh-high boots.

The 21-year-old kicked off the VMAs with a performance of "Break Free," off her new album, "My Everything." A couple of verses into the song she was joined by Nicki Minaj, who segued into her latest single, Anaconda, before Brit Jessie J joined in for a rendition of her hit "Bang Bang," which features both Grande and Minaj.

The video for Jessie J's "Bang Bang" debuted moments after the trio's performance on

At press time, Ariana had scooped up the Best Pop Video award for her single "Problem," featuring rapper Iggy Azalea.