We spotted Blake Lively shooting a fashion spread for Lucky Magazine in New York City on Monday. The actress wore a sexy little black dress, thigh-high peep-toe boots and a floppy hat for some of the shots.

She also donned mirrored sunglasses, a white leather jacket, and stilettos.

On Sunday night, the former "Gossip Girl" actress attended The "PUNK: Chaos to Couture" Costume Institute Gala at The Metropolitan Museum of Art.  Husband Ryan Reynolds did not pose on the red carpet with her.

It's been rumored that the star will play Freddie Mercury's former girlfriend Mary Austin in the upcoming biopic about the late Queen singer. Borat star Sacha Baron Cohen is playing the iconic singer.

In addition to her CW series, Blake most recently appeared in the big-screen films "Savages," "Green Lantern" and "The Town."

Check out more photos from Blake's Lucky photo shoot...